Eurowings launched its first flight from Berlin Tegel to Munich on May 1.
The flights operate four times a day during the week, and three times a day on weekends.
From May 17, a fifth flight will be added to the Friday timetable. Tickets are now available from €34,99 (R566) for one-way flights via eurowings.com or the Eurowings App.
The new Eurowings service complements Lufthansa's services on the route. The two airlines will offer more than 300 weekly flights between the two cities.